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Understanding Bisphenols and Phenols in Direct Thermal Label Coatings

How safer chemistry is shaping the next generation of direct thermal labels.

Direct thermal labels are widely used in logistics, retail and warehousing — but not all direct thermal papers are made the same. The chemistry used in their coatings has changed significantly in recent years, particularly with the move away from bisphenols such as BPA and BPS.

In this article, we explain what these terms mean, why the change matters, and how today’s materials provide reliable performance without relying on bisphenol chemistry.

Thermal labels printed from a desktop printer

What are Bisphenols and Phenols?

Bisphenols are chemical compounds historically used in thermal coatings to develop the printed image under heat. The most common were BPA (bisphenol A) and BPS (bisphenol S). Both belong to the broader group of phenolic compounds, some of which have raised environmental and health concerns due to their persistence and potential endocrine effects.

Why They Were Used

In traditional direct thermal materials, bisphenols acted as colour developers. When heat from the printer head was applied, these compounds reacted with other components in the coating to form the dark printed image. This provided sharp print contrast and fast response times, but the chemistry came under review as awareness of bisphenols grew.

Regulation and Reformulation

The use of BPA in thermal paper was restricted in the EU and UK from 2020, driving significant reformulation. Some products switched to BPS as a drop-in replacement, while others moved to completely new bisphenol-free chemistries. These newer coatings achieve high image stability and print quality without bisphenols or phenols.

Modern Alternatives

At North & South Labels, our Direct Thermal (DT) range includes two main grades:

  • DT Eco — an economical uncoated material that is BPA-free, suitable for general-purpose applications where moderate image life is sufficient.
  • DT Top-coated — a premium grade produced without bisphenol chemistry, making it BPA-, BPS- and phenol-free as standard, with enhanced resistance to heat, light and handling.

Choosing the Right Option

If your application involves regulated environments such as healthcare, food contact or long-term storage, we recommend specifying Top-coated Direct Thermal for maximum chemical compliance and image durability. For short-term logistics or general use, Eco grade materials remain a cost-effective, BPA-free solution.

Summary

Today’s direct thermal coatings have evolved well beyond their bisphenol-based origins. Whether your focus is sustainability, compliance or performance, modern materials now provide dependable results without bisphenol or phenol chemistry.

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